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Raoult’s Law for a single condensable species: If i is the condensable component, then at equilibrium the partial pressure of i in the gas mixture must equal the vapor pressure of the pure i liquid. This is called Raoult’s Law. In equation form, Pi = yiP = p * i (6) Notes: (i) Only a saturated vapor can condense. If a vapor is present in ...
Continue Reading...Transport Phenomena in Multiphase Systems by A. Faghri & Y. Zhang 1 Chapter 11: Two-Phase Flow and Heat Transfer 11.2 Flow Patterns of Liquid-Vapor (Gas)
Continue Reading...Esercitazione n. 11 - Reazioni degli alogenuri alchilici. TERMINI ED ARGOMENTI PER LO SVOLGIMENTO DEGLI ESERCIZI DI QUESTO FOGLIO: Meccanismi delle reazioni di sostituzione nucleofila al carbonio saturo (SN2, SN1). Meccanismi delle reazioni di ?-eliminazione (E2, E1). Orientamento di Saytzeff e di Hofmann. Trasposizione dei carbocationi.
Continue Reading...Una sostituzione nucleofila di secondo ordine è una reazione bimolecolare che segue una cinetica di secondo ordine, per cui la velocità di reazione dipende sia dalla concen-trazione dell’alogenuro che da quella dello ione OH?. b. Perché la sostituzione diretta del gruppo —OH con lo ione Cl? ha una resa bassissima e la reazio-
Continue Reading...Sostituzione nucleofila Sostituzione nucleofila 1 Il meccanismo della Sn1 prevede due stadi: il primo determina la velocità della reazione (stadio lento) e prevede la formazione di un carbocatione intermedio, mentre il secondo (stadio veloce) preede l’attao nu leofilo al aroatione he si è formato in pre edenza.
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